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Relevant publications

  • Buades, D. Moonshiram, T. PH Sidiropoulos, I. León, P. Schmidt, I. Pi, N. Di Palo, S. L Cousin, A. Picón, F. Koppens, J. Biegert. Attosecond dispersive soft X-ray absorption fine structure spectroscopy in graphite., Optica, 2018, 5(5), 502-506.
  • Moonshiram, P. Garrido-Barros, C. Gimbert-Surinach, A.Picon, C.Liu, X.Zhang, M. Karnahl, A. Llobet. Elucidating the nature of the excited state of a heteroleptic copper photosensitizer through time-resolved X-ray absorption spectroscopy., Chem. Eur. J, 2018, 24, 6464-6472.
  • Garrido-Barros, C. Gimbert-Suriñach, D. Moonshiram, A. Picón, P. Monge, V.S. Batista, A. Llobet. Electronic π-delocalization Boosts Catalytic Water Oxidation by Cu(II) Molecular Catalysts Heterogenized on Graphene Sheets., J. Am. Chem. Soc. 2017139, pp 12907-12910.
  • Moonshiram, A. Picón, A. Vasquez-Mayagotia, X. Zhang, M.F. Tu, P.Garrido-Barros, J.P.Mahy, F.Avenier, and A. Aukauloo. Elucidating the light-induced charge accumulation in an artificial analogue of methane monooxygenase enzymes using time-resolved X-ray absorption spectroscopy., Chem. Commun. 2017, 53, pp 2725-2728 (Chosen to be among Advanced Photon Source (APS) Research Highlights).
  • Moonshiram, Y. Pineda-Galvan, D. Erdman, M. Palenik, R. Thummel, and Y. Pushkar. Spectroscopic analysis of catalytic water oxidation by Ru complex – uncovering the facility of oxygen atom transfer.,J. Am. Chem. Soc. 2016138 (48), pp 15605–15616.
  • Gimbert-Surinach., DMoonshiram, LFrancas., N. Planas , F. Bozoglian, A. Guda, L. Mognon, I. Lopez, C.J. Cramer, L. Gagliardi, A. Llobet. Structural and Spectroscopic Characterization of Reaction Intermediates involved in a Dinuclear Co-Hbpp Water Oxidation Catalyst., J. Am. Chem. Soc. 2016138 (47), pp 15291–15294.
  • Creus., R. Matheu, I.Penafiel, D.Moonshiram, J. Benet-Buchholtz, J. Garcia-Anton, X. Sala, C. Godard, and A. Llobet. A Million Turnover Molecular Anode for Catalytic Water Oxidation., Angew. Chem. Int. Ed. 2016, 55 (49), pp 15382-15386.
  • Moonshiram, A. Guda, L. Kohler, A. Picón , S. Guda, C.S. Lehmann, X. Zhang, S. H. Southworth, and K. L. Mulfort. Mechanistic Evaluation of a Nickel Proton Reduction Catalyst through Time-resolved X-ray Absorption Spectroscopy., J. Phys. Chem. C. 2016, 120, pp 20049−20057.
  • Moonshiram, C. Gimbert Surinach, A. Guda, A. Picón, C. Stefan Lehmann, X. Zhang, G. Doumy, A. March, J. Benet-Buchholz, A.Soldatov, A. Llobet, and S. H. Southworth. Tracking the structural and electronic configurations of a cobalt proton reduction catalyst in water. J. Am. Chem. Soc.2016,138 (33), pp 10586–10596 (Chosen to be among Advanced Photon Source (APS) Research Highlights).
  • Pushkar, D. Moonshiram, V. Purohit, L. Yan, and I. Alperovich. Spectroscopic Analysis of Catalytic Water Oxidation by [RuII(bpy)(tpy)H2O]2+ Suggests That RuV═O Is Not a Rate-Limiting Intermediate., J. Am. Chem. Soc.2014, 136 (34), pp 11938-11945.
  • Moonshiram, I. Alperovich, J.J. Concepcion, T.J. Meyer, and Y. Pushkar. Experimental Demonstration of Radicaloid Character of RuV=O Moiety Reactive towards Formation of O-O bond., Proc. Natl. Acad. Sci.2013., 110 (10), 201, pp 3765-3370.