Extending, distorting and stacking nanographenes into 1D, 2D and 3D structures

Prof. Aurelio Mateo Alonso (University of the Basque Country UPV/EHU)

Tuesday, 18 March 2025 12:00

Place: conference hall, IMDEA Nanociencia.

Abstract:

Nanographenes are receiving a great deal of attention because of their increasing performance in organic electronic applications.The properties of nanographenes are dominated by several structural variables such as the number of fused rings, their arrangement and the presence of heteroatoms in the structure, among others. We have developed several synthetic strategies that give access to 1D,^[1] 2D^[2] and 3D^[3] structures constituted by nanographenes. The most recent advances of these structures including synthetic routes, optoelectronic properties, and potential applications will be discussed.

References

[1] a) D. Cortizo-Lacalle, J. P. Mora-Fuentes, K. Strutyński, A. Saeki, M. Melle-Franco, and A. Mateo-Alonso Angew. Chem. Int. Ed. 2018, 57, 703. b) R. K. Dubey, M. Melle-Franco, and A. Mateo-Alonso J. Am. Chem. Soc. 2021, 143, 6593. c) R. K. Dubey, M. Melle-Franco, and A. Mateo-Alonso J. Am. Chem. Soc. 2022, 144, 2765. d) M. Martínez-Abadía, R. K. Dubey, M. Fernández, M. Martín-Arroyo, R. Aguirresarobe, A. Saeki, and A. Mateo-Alonso Chem. Sci. 2022, 13, 10773. e) R. K. Dubey, M. Marongiu, S. Fu, G. Wen, M. Bonn, H. I. Wang, M. Melle-Franco, A. Mateo-Alonso Chem, 2023, 9, 2983-2996. f) M. Marongiu, T. Ha, S. Gil-Guerrero, K. Garg, M. Mandado, M. Melle-Franco, I. Diez-Perez, and A. Mateo-Alonso J. Am. Chem. Soc., 2024, 146, 3963–3973

[2] a) A. B. Marco, D. Cortizo-Lacalle, I. Perez-Miqueo, G. Valenti, A. Boni, J. Plas, S. De Feyter, F. Paolucci, M. Montes, A. Khlovystov, M. Melle-Franco and A. Mateo-Alonso Angew. Chem. Int. Ed. 2017, 56, 6946. b) M. Martínez-Abadía, C.T. Stoppiello, K. Strutynski, B. Lerma-Berlanga, C. Martí-Gastaldo, A. Saeki, M. Melle-Franco, A.N. Khlobystov and A. Mateo-Alonso J. Am. Chem. Soc. 2019, 141, 14403. c) A. Riaño, K. Strutyński, M. Liu, C. T. Stoppiello, B. Lerma-Berlanga, A. Saeki, C. Martí-Gastaldo, A. N. Khlobystov, G. Valenti, F. Paolucci, M. Melle-Franco, and A. Mateo-Alonso Angew. Chem. Int. Ed. 2022, 61, e202113657.

[3] M. Martínez-Abadía, K. Strutynski, B. Lerma-Berlanga, C. T. Stoppiello, A. N. Khlobystov, C. Martí-Gastaldo, A. Saeki, M. Melle-Franco, and A. Mateo-Alonso Angew. Chem. Int. Ed. 2021, 60, 9941.

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